The crystal structure of the Dess-Martin periodinane

Albert Schröckeneder; Desiree Stichnoth; Peter Mayer; Dirk Trauner

doi:10.3762/bjoc.8.172

The crystal structure of the Dess-Martin periodinane

Albert Schröckeneder, Desiree Stichnoth, Peter Mayer, Dirk Trauner

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We report the elusive X-ray structure of the Dess-Martin periodinane (DMP), a hypervalent iodine reagent popular amongst synthetic chemists. In the solid state, the highly crystalline compound forms an intricate coordination polymer held together by intermolecular halogen and hydrogen bonds.

Original language	English (US)
Pages (from-to)	1523-1527
Number of pages	5
Journal	Beilstein Journal of Organic Chemistry
Volume	8
DOIs	https://doi.org/10.3762/bjoc.8.172
State	Published - Sep 12 2012

Keywords

Crystal structure
Dess-Martin periodinane
Halogen bonds
Hypervalent iodine
Oxidant

ASJC Scopus subject areas

Organic Chemistry

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10.3762/bjoc.8.172

Cite this

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abstract = "We report the elusive X-ray structure of the Dess-Martin periodinane (DMP), a hypervalent iodine reagent popular amongst synthetic chemists. In the solid state, the highly crystalline compound forms an intricate coordination polymer held together by intermolecular halogen and hydrogen bonds.",

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AU - Trauner, Dirk

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KW - Halogen bonds

KW - Hypervalent iodine

KW - Oxidant

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The crystal structure of the Dess-Martin periodinane

Abstract

Keywords

ASJC Scopus subject areas

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