The effect of dehydration on the position of cesium cations in the structure of CsNaFAU(Y) studied by powder X-ray diffraction and magic-angle spinning NMR spectroscopy

O. A. Ponomareva; P. A. Kots; Yu G. Kolyagin; V. V. Chernyshev; I. I. Ivanova

doi:10.1007/s11172-017-1976-4

The effect of dehydration on the position of cesium cations in the structure of CsNaFAU(Y) studied by powder X-ray diffraction and magic-angle spinning NMR spectroscopy

O. A. Ponomareva, P. A. Kots, Yu G. Kolyagin, V. V. Chernyshev, I. I. Ivanova

Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

The influence of dehydration on the position of sodium and cesium cations obtained by ion exchange in the structure of FAU(Y) was studied by powder X-ray diffraction using synchrotron radiation and ²³Na and ¹³³Cs magic-angle spinning NMR spectroscopy. The sodium and cesium cations were found to be mobile in the hydrated samples. In dehydrated zeolites CsNaFAU(Y), cesium is predominantly localized in four crystallographic ion-exchange positions located in the large cavities and sodalite cages.

Original language	English (US)
Pages (from-to)	2021-2027
Number of pages	7
Journal	Russian Chemical Bulletin
Volume	66
Issue number	11
DOIs	https://doi.org/10.1007/s11172-017-1976-4
State	Published - Nov 1 2017

Keywords

cesium
FAU(Y)
ion exchange
magic-angle spinning NMR spectroscopy
powder X-ray diffraction

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1007/s11172-017-1976-4

Cite this

@article{822d99fe5ad64b52853a0d84e80a4a9b,

title = "The effect of dehydration on the position of cesium cations in the structure of CsNaFAU(Y) studied by powder X-ray diffraction and magic-angle spinning NMR spectroscopy",

abstract = "The influence of dehydration on the position of sodium and cesium cations obtained by ion exchange in the structure of FAU(Y) was studied by powder X-ray diffraction using synchrotron radiation and 23Na and 133Cs magic-angle spinning NMR spectroscopy. The sodium and cesium cations were found to be mobile in the hydrated samples. In dehydrated zeolites CsNaFAU(Y), cesium is predominantly localized in four crystallographic ion-exchange positions located in the large cavities and sodalite cages.",

keywords = "cesium, FAU(Y), ion exchange, magic-angle spinning NMR spectroscopy, powder X-ray diffraction",

author = "Ponomareva, {O. A.} and Kots, {P. A.} and Kolyagin, {Yu G.} and Chernyshev, {V. V.} and Ivanova, {I. I.}",

note = "Publisher Copyright: {\textcopyright} 2017, Springer Science+Business Media, LLC, part of Springer Nature.",

year = "2017",

month = nov,

day = "1",

doi = "10.1007/s11172-017-1976-4",

language = "English (US)",

volume = "66",

pages = "2021--2027",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer New York",

number = "11",

}

TY - JOUR

T1 - The effect of dehydration on the position of cesium cations in the structure of CsNaFAU(Y) studied by powder X-ray diffraction and magic-angle spinning NMR spectroscopy

AU - Ponomareva, O. A.

AU - Kots, P. A.

AU - Kolyagin, Yu G.

AU - Chernyshev, V. V.

AU - Ivanova, I. I.

PY - 2017/11/1

Y1 - 2017/11/1

N2 - The influence of dehydration on the position of sodium and cesium cations obtained by ion exchange in the structure of FAU(Y) was studied by powder X-ray diffraction using synchrotron radiation and 23Na and 133Cs magic-angle spinning NMR spectroscopy. The sodium and cesium cations were found to be mobile in the hydrated samples. In dehydrated zeolites CsNaFAU(Y), cesium is predominantly localized in four crystallographic ion-exchange positions located in the large cavities and sodalite cages.

AB - The influence of dehydration on the position of sodium and cesium cations obtained by ion exchange in the structure of FAU(Y) was studied by powder X-ray diffraction using synchrotron radiation and 23Na and 133Cs magic-angle spinning NMR spectroscopy. The sodium and cesium cations were found to be mobile in the hydrated samples. In dehydrated zeolites CsNaFAU(Y), cesium is predominantly localized in four crystallographic ion-exchange positions located in the large cavities and sodalite cages.

KW - cesium

KW - FAU(Y)

KW - ion exchange

KW - magic-angle spinning NMR spectroscopy

KW - powder X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=85044007791&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85044007791&partnerID=8YFLogxK

U2 - 10.1007/s11172-017-1976-4

DO - 10.1007/s11172-017-1976-4

M3 - Article

AN - SCOPUS:85044007791

SN - 1066-5285

VL - 66

SP - 2021

EP - 2027

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 11

ER -

The effect of dehydration on the position of cesium cations in the structure of CsNaFAU(Y) studied by powder X-ray diffraction and magic-angle spinning NMR spectroscopy

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this