Abstract
The nonadiabatic reaction of F( 2P 3/2, 2P 1/2) with H 2 and D 29,30 2 on the Alexander-Stark-Werner potential energy surface, was investigated using the time-dependent quantum wave packet method. The initial state-resolved reactive integral cross sections were determined by summing the reaction probabilities over all the partial waves. The branching ratios and the energy-dependent reactivity of the excited spin-orbit state for the two possible products, were calculated using the cross sections. The results show that at high collision energy, the reactivity of the excited spin-orbit state for the two possible products is no more than 43% of reativity of the ground spin-orbit state.
Original language | English (US) |
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Pages (from-to) | 6000-6004 |
Number of pages | 5 |
Journal | Journal of Chemical Physics |
Volume | 120 |
Issue number | 13 |
DOIs | |
State | Published - Apr 1 2004 |
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry