The Rise of the Dynamic Crystals

Panče Naumov, Durga Prasad Karothu, Ejaz Ahmed, Luca Catalano, Patrick Commins, Jad Mahmoud Halabi, Marieh B. Al-Handawi, Liang Li

Research output: Contribution to journalArticle

Abstract

The anticipated shift in the focal point of interest of solid-state chemists, crystal engineers, and crystallographers from structure to properties to function parallels the need to apply our accumulated understanding of the intricacies of crystal structure to explaining the related properties, with the ultimate goal of harnessing that knowledge in applications that require soft, lightweight, or biocompatible organic solids. In these developments, the adaptive molecular crystals warrant particular attention as an alternative choice of materials for light, flexible, and environmentally benign devices, primarily memories, capacitors, sensors, and actuators. Some of the outstanding requirements for the application of these dynamic materials as high-efficiency energy-storage devices are strongly induced polarization, a high switching field, and narrow hysteresis in the case of reversible dynamic processes. However, having been studied almost exclusively by chemists, molecular crystals still lack the appropriate investigations that reliably evaluate their reproducibility, scalability, and actuating performance, and some important drawbacks have diverted the interest of engineers from these materials in applications. United under the umbrella term crystal adaptronics, the recent research efforts aim to realistically assess the appositeness of dynamic crystals for applications that require fast, reversible, and continuous operation over prolonged periods of time. With the aim of highlighting the most recent developments, this Perspective discusses their assets and pitfalls. It also provides some hints on the likely future developments that capitalize on the untapped, sequestered potential of this distinct materials class for applications.

Original languageEnglish (US)
Pages (from-to)13256-13272
Number of pages17
JournalJournal of the American Chemical Society
Volume142
Issue number31
DOIs
StatePublished - Aug 5 2020

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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  • Cite this

    Naumov, P., Karothu, D. P., Ahmed, E., Catalano, L., Commins, P., Mahmoud Halabi, J., Al-Handawi, M. B., & Li, L. (2020). The Rise of the Dynamic Crystals. Journal of the American Chemical Society, 142(31), 13256-13272. https://doi.org/10.1021/jacs.0c05440