The thermal decomposition of the pyridine saccharinates of Co, Ni and Cu: A correlation of the structural and the infrared data

Panče Naumov; Gligor Jovanovski; Vera Jordanovska; Boyan Boyanov

doi:10.2298/jsc9910609n

The thermal decomposition of the pyridine saccharinates of Co, Ni and Cu: A correlation of the structural and the infrared data

Panče Naumov, Gligor Jovanovski, Vera Jordanovska, Boyan Boyanov

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In order to investigate the differences in the stability of the isomorphous pyridine saccharinates [Co(H₂O)₄(C₅H₅N)₂](C ₇H₄NO₃S)₂·4H₂O and [Ni(H₂O)₄(C₅H₅N)₂] (C₇H₄NO₃S)₂·4H₂O, their thermal behavior (TG, DTG and DTA curves) from ambient temperature up to 1000 °C in a static air atmosphere was studied. For comparative purposes, the thermoanalytical curves of [Cu(H₂O)(C₅H₅N)₂(C₇H ₄NO₃S)₂] were recorded as well. The decomposition pathways and the stability of the compounds are interpreted in the terms of the structural data. A possible mechanism for the decomposition of the saccharinato ion/ligand in an oxidizing atmosphere is proposed. The infrared spectral characteristics of the complexes are also discussed.

Original language	English (US)
Pages (from-to)	609-620
Number of pages	12
Journal	Journal of the Serbian Chemical Society
Volume	64
Issue number	10
DOIs	https://doi.org/10.2298/jsc9910609n
State	Published - 1999

Keywords

Infrared spectra
Pyridine complexes
Saccharinates
Structure
Thermal decomposition

ASJC Scopus subject areas

General Chemistry

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title = "The thermal decomposition of the pyridine saccharinates of Co, Ni and Cu: A correlation of the structural and the infrared data",

abstract = "In order to investigate the differences in the stability of the isomorphous pyridine saccharinates [Co(H2O)4(C5H5N)2](C 7H4NO3S)2·4H2O and [Ni(H2O)4(C5H5N)2] (C7H4NO3S)2·4H2O, their thermal behavior (TG, DTG and DTA curves) from ambient temperature up to 1000 °C in a static air atmosphere was studied. For comparative purposes, the thermoanalytical curves of [Cu(H2O)(C5H5N)2(C7H 4NO3S)2] were recorded as well. The decomposition pathways and the stability of the compounds are interpreted in the terms of the structural data. A possible mechanism for the decomposition of the saccharinato ion/ligand in an oxidizing atmosphere is proposed. The infrared spectral characteristics of the complexes are also discussed.",

keywords = "Infrared spectra, Pyridine complexes, Saccharinates, Structure, Thermal decomposition",

author = "Pan{\v c}e Naumov and Gligor Jovanovski and Vera Jordanovska and Boyan Boyanov",

year = "1999",

doi = "10.2298/jsc9910609n",

language = "English (US)",

volume = "64",

pages = "609--620",

journal = "Journal of the Serbian Chemical Society",

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publisher = "Serbian Chemical Society",

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T1 - The thermal decomposition of the pyridine saccharinates of Co, Ni and Cu

T2 - A correlation of the structural and the infrared data

AU - Naumov, Panče

AU - Jovanovski, Gligor

AU - Jordanovska, Vera

AU - Boyanov, Boyan

PY - 1999

Y1 - 1999

N2 - In order to investigate the differences in the stability of the isomorphous pyridine saccharinates [Co(H2O)4(C5H5N)2](C 7H4NO3S)2·4H2O and [Ni(H2O)4(C5H5N)2] (C7H4NO3S)2·4H2O, their thermal behavior (TG, DTG and DTA curves) from ambient temperature up to 1000 °C in a static air atmosphere was studied. For comparative purposes, the thermoanalytical curves of [Cu(H2O)(C5H5N)2(C7H 4NO3S)2] were recorded as well. The decomposition pathways and the stability of the compounds are interpreted in the terms of the structural data. A possible mechanism for the decomposition of the saccharinato ion/ligand in an oxidizing atmosphere is proposed. The infrared spectral characteristics of the complexes are also discussed.

AB - In order to investigate the differences in the stability of the isomorphous pyridine saccharinates [Co(H2O)4(C5H5N)2](C 7H4NO3S)2·4H2O and [Ni(H2O)4(C5H5N)2] (C7H4NO3S)2·4H2O, their thermal behavior (TG, DTG and DTA curves) from ambient temperature up to 1000 °C in a static air atmosphere was studied. For comparative purposes, the thermoanalytical curves of [Cu(H2O)(C5H5N)2(C7H 4NO3S)2] were recorded as well. The decomposition pathways and the stability of the compounds are interpreted in the terms of the structural data. A possible mechanism for the decomposition of the saccharinato ion/ligand in an oxidizing atmosphere is proposed. The infrared spectral characteristics of the complexes are also discussed.

KW - Infrared spectra

KW - Pyridine complexes

KW - Saccharinates

KW - Structure

KW - Thermal decomposition

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U2 - 10.2298/jsc9910609n

DO - 10.2298/jsc9910609n

M3 - Article

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SN - 0352-5139

VL - 64

SP - 609

EP - 620

JO - Journal of the Serbian Chemical Society

JF - Journal of the Serbian Chemical Society

IS - 10

ER -

The thermal decomposition of the pyridine saccharinates of Co, Ni and Cu: A correlation of the structural and the infrared data

Abstract

Keywords

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