The thermal decomposition of the pyridine saccharinates of Co, Ni and Cu: A correlation of the structural and the infrared data

Panče Naumov, Gligor Jovanovski, Vera Jordanovska, Boyan Boyanov

Research output: Contribution to journalArticlepeer-review

Abstract

In order to investigate the differences in the stability of the isomorphous pyridine saccharinates [Co(H2O)4(C5H5N)2](C 7H4NO3S)2·4H2O and [Ni(H2O)4(C5H5N)2] (C7H4NO3S)2·4H2O, their thermal behavior (TG, DTG and DTA curves) from ambient temperature up to 1000 °C in a static air atmosphere was studied. For comparative purposes, the thermoanalytical curves of [Cu(H2O)(C5H5N)2(C7H 4NO3S)2] were recorded as well. The decomposition pathways and the stability of the compounds are interpreted in the terms of the structural data. A possible mechanism for the decomposition of the saccharinato ion/ligand in an oxidizing atmosphere is proposed. The infrared spectral characteristics of the complexes are also discussed.

Original languageEnglish (US)
Pages (from-to)609-620
Number of pages12
JournalJournal of the Serbian Chemical Society
Volume64
Issue number10
DOIs
StatePublished - 1999

Keywords

  • Infrared spectra
  • Pyridine complexes
  • Saccharinates
  • Structure
  • Thermal decomposition

ASJC Scopus subject areas

  • Chemistry(all)

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