Theoretical investigations of l = 5/2 quadrupolar spin dynamics in the sudden-passage regime

Jamie D. Walls; Kwang Hun Lim; John W. Logan; Jeffry T. Urban; Alexej Jerschow; Alexander Pines

doi:10.1063/1.1483256

Theoretical investigations of l = 5/2 quadrupolar spin dynamics in the sudden-passage regime

Jamie D. Walls, Kwang Hun Lim, John W. Logan, Jeffry T. Urban, Alexej Jerschow, Alexander Pines

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The theoretical investigations of quadrupolar spin dynmaics was studied using bimodal Floquet theory. Effective transfer between five-quantum and triple-quantum coherences was observed in between rotary resonance conditions. The results revealed that rotary resonance effects occur when the strength of the radio-frequency irradiation matches the sample spinning speed.

Original language	English (US)
Pages (from-to)	518-532
Number of pages	15
Journal	Journal of Chemical Physics
Volume	117
Issue number	2
DOIs	https://doi.org/10.1063/1.1483256
State	Published - Jul 8 2002

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1483256

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abstract = "The theoretical investigations of quadrupolar spin dynmaics was studied using bimodal Floquet theory. Effective transfer between five-quantum and triple-quantum coherences was observed in between rotary resonance conditions. The results revealed that rotary resonance effects occur when the strength of the radio-frequency irradiation matches the sample spinning speed.",

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AU - Jerschow, Alexej

AU - Pines, Alexander

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Theoretical investigations of l = 5/2 quadrupolar spin dynamics in the sudden-passage regime

Abstract

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