Total synthesis of coralloidolides A, B, C, and E

Thomas J. Kimbrough; Paul A. Roethle; Peter Mayer; Dirk Trauner

doi:10.1002/anie.200906126

Total synthesis of coralloidolides A, B, C, and E

Thomas J. Kimbrough, Paul A. Roethle, Peter Mayer, Dirk Trauner

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

"Chemical Equation Presented" Mapping the matrix: Several coralloidolides, members of a Mediterranean branch of the furanocembranoid family of diterpenes, have been synthesized. The total syntheses include biomimetic transformations that often occur with high chemoselectivity, thus obviating the need for protecting-group manipulations. The fascinating reactivity of 2,5-diene-1,4dione moieties was explored in detail.

Original language	English (US)
Pages (from-to)	2619-2621
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	14
DOIs	https://doi.org/10.1002/anie.200906126
State	Published - Mar 29 2010

Keywords

Biomimetic synthesis
Chemoselectivity
Furanocembranoids
Lewis acids
Total synthesis

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200906126

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AU - Roethle, Paul A.

AU - Mayer, Peter

AU - Trauner, Dirk

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Y1 - 2010/3/29

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KW - Biomimetic synthesis

KW - Chemoselectivity

KW - Furanocembranoids

KW - Lewis acids

KW - Total synthesis

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Total synthesis of coralloidolides A, B, C, and E

Abstract

Keywords

ASJC Scopus subject areas

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