Abstract
The total synthesis of the diterpenoids sandresolide B and amphilectolide from a common furan building block is presented. Key steps include palladium-mediated carbonylation, lanthanide catalyzed ring closure, Myers alkylation, intramolecular Friedel-Crafts acylation, photooxygenation, and a Kornblum-DeLaMare rearrangement.
Original language | English (US) |
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Pages (from-to) | 166-169 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 16 |
Issue number | 1 |
DOIs | |
State | Published - Jan 3 2014 |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry