Abstract
A reputation restored: Eligio Perucca (see photo) first observed the enantioselective adsorption of a racemic mixture to a chiral crystal (NaClO 3) in Turin in 1919. However, this milestone in enantioselective chemistry and chiroptics went unnoticed. Identified previously as a coward who refused in 1941 to supervise the research of the budding stereochemist Primo Levi because of the race laws, Perucca was opposed to the fascist regime.
Original language | English (US) |
---|---|
Pages (from-to) | 3744-3748 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 48 |
Issue number | 21 |
DOIs | |
State | Published - May 11 2009 |
Keywords
- Chirality
- Circular dichroism
- Dyes/pigments
- Enantioselectivity
- Optical rotatory dispersion
ASJC Scopus subject areas
- Catalysis
- General Chemistry