Using stereoelectronic effects to explain selective reactions of 4-substituted five-membered ring oxocarbenium ions

Deborah M. Smith; K. A. Woerpel

doi:10.1021/ol0492647

Using stereoelectronic effects to explain selective reactions of 4-substituted five-membered ring oxocarbenium ions

Deborah M. Smith, K. A. Woerpel

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Equation presented. The utility of the inside attack model to predict and analyze the stereoselectivities of nucleophilic additions to complex five-membered ring oxocarbenium ions is demonstrated in a systematic study of C-4-substituted acetals.

Original language	English (US)
Pages (from-to)	2063-2066
Number of pages	4
Journal	Organic Letters
Volume	6
Issue number	12
DOIs	https://doi.org/10.1021/ol0492647
State	Published - Jun 10 2004

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol0492647

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title = "Using stereoelectronic effects to explain selective reactions of 4-substituted five-membered ring oxocarbenium ions",

abstract = "Equation presented. The utility of the inside attack model to predict and analyze the stereoselectivities of nucleophilic additions to complex five-membered ring oxocarbenium ions is demonstrated in a systematic study of C-4-substituted acetals.",

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N2 - Equation presented. The utility of the inside attack model to predict and analyze the stereoselectivities of nucleophilic additions to complex five-membered ring oxocarbenium ions is demonstrated in a systematic study of C-4-substituted acetals.

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Using stereoelectronic effects to explain selective reactions of 4-substituted five-membered ring oxocarbenium ions

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