Visible light-induced transition metal-catalyzed transformations: Beyond conventional photosensitizers

Marvin Parasram, Vladimir Gevorgyan

Research output: Contribution to journalReview articlepeer-review

Abstract

Employment of simple transition metal (TM = Co, Fe, Cu, Pd, Pt, Au)-based photocatalyst (PC) has led to the dramatic acceleration of known TM-catalyzed reactions, as well as to the discovery of unprecedented chemical transformations. Compared to the conventional cooperative/dual photocatalysis (type B), this new class of unconventional PCs operates via a single photoexcitation/catalytic cycle, where the TM complex plays a "double duty" role by harvesting light and catalyzing the chemical transformation. Also, these TM photocatalysts participate in the bond-forming/breaking event in the transformation via a substrate-TM interaction, an aspect that is uncommon for conventional photocatalysis (type A). This tutorial review highlights the recent advances in this emerging area.

Original languageEnglish (US)
Pages (from-to)6227-6240
Number of pages14
JournalChemical Society Reviews
Volume46
Issue number20
DOIs
StatePublished - Oct 21 2017

ASJC Scopus subject areas

  • Chemistry(all)

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