X-ray absorption spectroscopic studies of ruthenium-octaethylporphyrin dimers

Hitoshi Asahina, Matthew B. Zisk, Britt Hedman, John T. McDevitt, James P. Collman, Keith O. Hodgson

Research output: Contribution to journalArticle

Abstract

A series of metal-metal bonded dimeric ruthenium porphyrin complexes have been characterized by means of X-ray absorption spectroscopy, Ru-Ru bond lengths for Ru2.5+ and Ru3+ complexes having been determined by EXAFS to be 2.29 and 2.22 Å, respectively; electronic configurations also have been confirmed by X-ray absorption near edge spectroscopy.

Original languageEnglish (US)
Pages (from-to)1360-1362
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number18
DOIs
StatePublished - 1989

ASJC Scopus subject areas

  • Molecular Medicine

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