X-ray absorption spectroscopic studies of ruthenium-octaethylporphyrin dimers

Hitoshi Asahina; Matthew B. Zisk; Britt Hedman; John T. McDevitt; James P. Collman; Keith O. Hodgson

doi:10.1039/C39890001360

X-ray absorption spectroscopic studies of ruthenium-octaethylporphyrin dimers

Hitoshi Asahina, Matthew B. Zisk, Britt Hedman, John T. McDevitt, James P. Collman, Keith O. Hodgson

Research output: Contribution to journal › Article › peer-review

Abstract

A series of metal-metal bonded dimeric ruthenium porphyrin complexes have been characterized by means of X-ray absorption spectroscopy, Ru-Ru bond lengths for Ru^2.5+ and Ru³⁺ complexes having been determined by EXAFS to be 2.29 and 2.22 Å, respectively; electronic configurations also have been confirmed by X-ray absorption near edge spectroscopy.

Original language	English (US)
Pages (from-to)	1360-1362
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/C39890001360
State	Published - 1989

ASJC Scopus subject areas

Molecular Medicine

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title = "X-ray absorption spectroscopic studies of ruthenium-octaethylporphyrin dimers",

abstract = "A series of metal-metal bonded dimeric ruthenium porphyrin complexes have been characterized by means of X-ray absorption spectroscopy, Ru-Ru bond lengths for Ru2.5+ and Ru3+ complexes having been determined by EXAFS to be 2.29 and 2.22 {\AA}, respectively; electronic configurations also have been confirmed by X-ray absorption near edge spectroscopy.",

author = "Hitoshi Asahina and Zisk, {Matthew B.} and Britt Hedman and McDevitt, {John T.} and Collman, {James P.} and Hodgson, {Keith O.}",

year = "1989",

doi = "10.1039/C39890001360",

language = "English (US)",

pages = "1360--1362",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "18",

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T1 - X-ray absorption spectroscopic studies of ruthenium-octaethylporphyrin dimers

AU - Asahina, Hitoshi

AU - Zisk, Matthew B.

AU - Hedman, Britt

AU - McDevitt, John T.

AU - Collman, James P.

AU - Hodgson, Keith O.

PY - 1989

Y1 - 1989

N2 - A series of metal-metal bonded dimeric ruthenium porphyrin complexes have been characterized by means of X-ray absorption spectroscopy, Ru-Ru bond lengths for Ru2.5+ and Ru3+ complexes having been determined by EXAFS to be 2.29 and 2.22 Å, respectively; electronic configurations also have been confirmed by X-ray absorption near edge spectroscopy.

AB - A series of metal-metal bonded dimeric ruthenium porphyrin complexes have been characterized by means of X-ray absorption spectroscopy, Ru-Ru bond lengths for Ru2.5+ and Ru3+ complexes having been determined by EXAFS to be 2.29 and 2.22 Å, respectively; electronic configurations also have been confirmed by X-ray absorption near edge spectroscopy.

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DO - 10.1039/C39890001360

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AN - SCOPUS:37049081608

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 18

ER -

X-ray absorption spectroscopic studies of ruthenium-octaethylporphyrin dimers

Abstract

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